Chemical Engineering
Ahmed Zoeir; Alireza Tabatabaei Nejad; Elnaz Khodapanah
Abstract
In sour gas flares, content like any other components in inlet gas influences adiabatic flame temperature, which, in turn, impacts on the pollutant emission. Wherever flame temperature increases, the endothermic reaction between and is accelerated, which means higher emission ...
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In sour gas flares, content like any other components in inlet gas influences adiabatic flame temperature, which, in turn, impacts on the pollutant emission. Wherever flame temperature increases, the endothermic reaction between and is accelerated, which means higher emission to the atmosphere. In this work, we developed an in-house MATLAB code to provide an environment for combustion calculations. Then, this written code was used to perform sensitivity analyses on content, air temperature, and excess air ratio in sour gas flares. We used Environmental Protection Agency (EPA) reports to assign weighting indexes to each air contaminant according to its harmfulness to environment; thereafter, sour gas flaring conditions were optimized for two real field case studies, namely Ahwaz (AMAK) and South Pars, to reach the minimum integrated pollutant concentrations. The results show that each 2% increase in the content of the entrance feed may produce 0.3% additional in the exhaust. The results also confirm that decreases of 20 °F and 50 °F in the oxidant temperature cause emission to reduce by 0.5% to 1% respectively. Finally, to verify and validate our results acquired from the written MATLAB code, FRNC 2012 industrial software was used to duplicate the oxidation results for the two sour flare case studies.
Reza Behnood; Bagher Anvaripour; Nematollah Jaafarzade Haghighi Fard; Masoumeh Farasati
Abstract
In last decades, oil spill pollution has become an important issue of concern due to its serious environmental impacts; therefore, necessary actions should be taken to prevent or reduce these types of pollution and their environmental consequences. Natural organic sorbents are emerging as proper choices ...
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In last decades, oil spill pollution has become an important issue of concern due to its serious environmental impacts; therefore, necessary actions should be taken to prevent or reduce these types of pollution and their environmental consequences. Natural organic sorbents are emerging as proper choices for oil spill cleanup due to their availability, eco-friendliness, and low cost. In this study, phragmites australis, sugarcane leaves straw, and sugarcane bagasse were used for crude oil sorption in dry (only oil) systems. The results indicated that sugarcane bagasse had a higher oil sorption capacity compared to the others. Therefore, sugarcane bagasse was selected as the preferred sorbent and the effects of sorbent contact time and its particle size on oil adsorption capacity were evaluated for the systems of dry and crude oil layer on water. The results showed that the maximum adsorption capacity of raw sugarcane bagasse for dry system and crude oil layer system was about 8 and 6.6 gram crude oil per gram sorbent respectively.
Sadegh Mahmoudi; Abdonabi Hashemi; Shahin Kord
Abstract
This work is a primary achievement in studying the CO2 and N2–oil systems. To predict gas-liquid relative permeability curves, a Shan-Chen type multicomponent multiphase lattice Boltzmann model for two-phase flow through 2D porous media is developed. Periodic and bounce back boundary conditions ...
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This work is a primary achievement in studying the CO2 and N2–oil systems. To predict gas-liquid relative permeability curves, a Shan-Chen type multicomponent multiphase lattice Boltzmann model for two-phase flow through 2D porous media is developed. Periodic and bounce back boundary conditions are applied to the model with the Guo scheme for the external body force (i.e., the pressure gradient). The influence of relationship between cohesion and adsorption parameters and the interfacial tension values in Young's equation, pore structure (micro scan image derived porous media response is compared with corresponding porosity and permeability ideal sphere pack structure), and saturation distribution on relative permeability curves are studied with the aim to achieve the realistic stable condition for the simulation of gas-liquid systems with a low viscosity ratio.
Maryam Pahlavan; Mohammad Ali Fanaei
Abstract
Reaction furnace is the most important part of the Claus sulfur recovery unit and its performance has a significant impact on the process efficiency. Too many reactions happen in the furnace and their kinetics and mechanisms are not completely understood; therefore, modeling reaction furnace is difficult ...
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Reaction furnace is the most important part of the Claus sulfur recovery unit and its performance has a significant impact on the process efficiency. Too many reactions happen in the furnace and their kinetics and mechanisms are not completely understood; therefore, modeling reaction furnace is difficult and several works have been carried out on in this regard so far. Equilibrium models are commonly used to simulate the furnace, but the related literature states that the outlet of furnace is not in equilibrium and the furnace reactions are controlled by kinetic laws; therefore, in this study, the reaction furnace is simulated by a kinetic model. The predicted outlet temperature and concentrations by this model are compared with experimental data published in the literature and the data obtained by PROMAX V2.0 simulator. The results show that the accuracy of the proposed kinetic model and PROMAX simulator is almost similar, but the kinetic model used in this paper has two importance abilities. Firstly, it is a distributed model and can be used to obtain the temperature and concentration profiles along the furnace. Secondly, it is a dynamic model and can be used for analyzing the transient behavior and designing the control system.
Morteza Azadpour; Navid Shad Manaman
Abstract
Pore pressureis defined as the pressure of the fluid inside the pore space of the formation, which is also known as the formation pressure. When the pore pressure is higher than hydrostatic pressure, it is referred to as overpressure. Knowledge of this pressure is essential for cost-effective drilling, ...
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Pore pressureis defined as the pressure of the fluid inside the pore space of the formation, which is also known as the formation pressure. When the pore pressure is higher than hydrostatic pressure, it is referred to as overpressure. Knowledge of this pressure is essential for cost-effective drilling, safe well planning, and efficient reservoir modeling. The main objective of this study is to estimate the formation pore pressure as a reliable mud weight pressure using well log data at one of oil fields in the south of Iran. To obtain this goal, the formation pore pressure is estimated from well logging data by applying Eaton’s prediction method with some modifications. In this way, sonic transient time trend line is separated by lithology changes and recalibrated by Weakley’s approach. The created sonic transient time is used to create an overlay pore pressure based on Eaton’s method and is led to pore pressure determination. The results are compared with the pore pressure estimated from commonly used methods such as Eaton’s and Bowers’s methods. The determined pore pressure from Weakley’s approach shows some improvements in comparison with Eaton’s method. However, the results of Bowers’s method, in comparison with the other two methods, show relatively better agreement with the mud weight pressure values.
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