Document Type : Research Paper

Authors

• behrouz Bayati ¹
• pardis morshedi ²
• Akbar Falahi ²
• Towan Kikhavandi ²

¹ Chemical Engineering Department, Faculty of Engineering, Ilam University, Ilam, Iran

² Ilam University

Abstract

HThe formation of heat stable salts, such as acetate, formate, oxalate, and thiosulfate, in gas sweetening units creates various issues including corrosion, high foaming, and a reduction in unit efficiency. This research aimed to investigate the elimination of heat stable salts using an anion resin. The findings indicate that it is feasible to remove approximately 85% of acetate anion salt from an amine solution at solution-to-resin ratio of 30. Two adsorption models, Langmuir and Freundlich, were employed to analyze the equilibrium adsorption of acetate anion salt. The results indicate that the Langmuir adsorption isotherm aligns more closely with the data obtained from the acetate anion ion exchange process with the resin. Furthermore, it was determined that the maximum adsorption capacity for acetate onto the resin is 15 mg/g at a temperature of 25°C. The impact of contact time during the adsorption process was examined using quasi-first-order and quasi-second-order kinetic models, as well as an intra-particle model. The results indicated that the quasi-first-order kinetic model provided the best fit to the data, and equilibrium adsorption was achieved after approximately 70 minutes. Thermodynamic parameters were also investigated, revealing a ΔH value of -12.7370 kJ/mol, indicating an exothermic adsorption process. Based on the conducted studies, the utilization of the selected resin appears to be a suitable option for the removal of heat stable salts.

Keywords

• ion-exchange resin
• heat stable salts (HSS)
• adsorption equilibrium isotherms
• kinetics
• thermodynamic parameters

Main Subjects

• Chemical Engineering