Electrodeposition of Homogeneous and Functionally Graded Ni-Co/SiC Nanostructured Coatings: Erosion, Wear, and Corrosion Behavior

Document Type : Research Paper

Authors

1 PhD Student, Department of Materials Science and Engineering, Faculty of Engineering, Shahid Chamran University of Ahvaz, Ahvaz, Iran Iran

2 Associate Professor, Department of Materials Science and Engineering, Faculty of Engineering, Shahid Chamran University of Ahvaz, Ahvaz, Iran

Abstract
In this study, nanostructured homogeneous and functionally graded (FG) Ni-Co/SiC coatings were fabricated on aluminum substrates via electrodeposition using a square pulse current. The FG coating was produced by continuously varying the concentration of SiC particles (0–40 g/L) in the electrolyte, resulting in a graded particle distribution across the coating thickness. The microstructure and morphology of the coatings were characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD). Mechanical and electrochemical properties were evaluated through microhardness testing, T-peel adhesion testing, pin-on-disk wear testing, erosion testing, and potentiodynamic polarization and impedance spectroscopy. The results revealed that the SiC content in the FG coating gradually increased from 0 wt.% at the substrate interface to 6 wt.% at the surface. Compared to the homogeneous Ni-Co/SiC coatings, the FG coating demonstrated 40% higher adhesion strength and twice the wear resistance. Additionally, the FG coating exhibited improved corrosion resistance and overall mechanical performance, highlighting its potential for demanding industrial applications.

Highlights

·       Functionally graded Ni–Co/SiC coatings exhibit 40% higher adhesion strength and approximately twofold greater wear resistance compared with homogeneous coatings.

·       A graded SiC distribution ranging from 0 to 6 wt.% enhances interfacial bonding, hardness, and corrosion resistance.

·       The Ni–Co/SiC tribolayer coating promotes stable sliding wear behavior, thereby significantly improving durability in industrial environments.

Keywords

Subjects

Allahyarzadeh, M. H., Aliofkhazraei, M., Rouhaghdam, A. R, and Torabinejad, V., Gradient electrodeposition of Ni-Cu-W(alumina) nanocomposite coating, Materials and Design, Vol. 107, p. 74–81, 2016.
Aruna, S. T., Bindu, C. N., Selvi, V. E., William Grips, V. K., and Rajam, K. S., Synthesis and properties of electrodeposited Ni/ceria nanocomposite coatings, Surface and Coatings Technology, Vol. 200, p. 6871–6880, 2006.
Cavaliere, P., Crack tip plasticity in plastically graded Ni-W electrodeposited nanocrystalline alloys, Computational Materials Science, Vol. 41, p. 440–449, 2008.
Chen, X. H., Chen, C. S., Xiao, H. N., Cheng, F. Q., Zhang, G., and Yi, G. J., Corrosion behavior of carbon nanotubes–Ni composite coating, Surface and Coatings Technology, Vol. 191, p. 351–356, 2005.
Choi, I. S., Detor, A. J., Schwaiger, R., Dao, M., Schuh, C. A., and Suresh, S., Mechanics of indentation of plastically graded materials-II: Experiments on nanocrystalline alloys with grain size gradients, Journal of the Mechanics and Physics of Solids, Vol. 56, p. 172–183, 2008.
Dong, Y. S., Lin, P. H., and Wang, H. X., Electroplating preparation of Ni–Al2O3 graded composite coatings using a rotating cathode, Surface and Coatings Technology, Vol. 200, p. 3633–3636, 2006.
Holmberg, K., Matthews, A., and Ronkainen, H., Coatings tribology: Contact mechanisms and surface design, Tribology International, Vol. 31, p. 107–120, 1998.
Hou, K. H., Ger, M. D., Wang, L. M., and Ke, S. T., The wear behavior of electrocodeposited Ni–SiC composites, Wear, Vol. 253, p. 994–1003, 2002.
Jiang, W., Shen, L., Xu, M., Wang, Z., and Tian, Z., Mechanical properties and corrosion resistance of Ni-Co-SiC composite coatings by magnetic field-induced jet electrodeposition, Journal of Alloys and Compounds, Vol. 791, p. 847–855, 2019.
Kim, S. K., and Yoo, H. J., Formation of bilayer Ni–SiC composite coatings by electrodeposition, Surface and Coatings Technology, Vol. 108–109, p. 564–569, 1998.
Lecina, E. G., Urrutia, I. G., Dıez, J.A., Salvo, M., Smeacetto, F., Gautier, Seddon, G. R., Martin, R., Electrochemical preparation and characterization of Ni/SiC compositionally graded multilayered coatings, Electrochimica Acta, Vol. 54, p. 2556–2562, 2009.
Leszek, L., Lech, P., Marcin, W., Pawel, S., Aleksandra, M., and Stefan, K., Review of Functionally Graded Thermal Sprayed Coatings, Applied Sciences, Vol. 10, No. 15, Article 5153, 2020.
Liu, Y., Luquan, R., Sirong, Y., and Zhuwu, H., Influence of current density on nano-Al2O3/Ni-Co bionic gradient composite coatings by electrodeposition, Journal of University of Science and Technology Beijing, Vol. 15, p. 633–637, 2008.
Meng, G., Shao, Y., Zhang, T., Zhang, Y., and Wang, F., Synthesis and corrosion property of pure Ni with a high density of nanoscale twins, Electrochimica Acta, Vol. 53, p. 5923–5926, 2008.
Mishra, R., and Balasubramaniam, R., Effect of nanocrystalline grain size on the electrochemical and corrosion behavior of nickel, Corrosion Science, Vol. 46, p. 3019–3029, 2004.
Orlovskaja, L., Periene, N., Kurtinaitiene, M., and Bikulcius, G., Electrocomposites with SiC content modulated in layers, Surface and Coatings Technology, Vol. 105, p. 8–12, 1998.
Pavlatou, E. A., Stroumbouli, M., Gyftou, P., and Spyrellis, N., Hardening effect induced by incorporation of SiC particles in nickel electrodeposits, Journal of Applied Electrochemistry, Vol. 36, p. 385–394, 2006.
Pei, Y. T., Ocelik, V., and De Hosson, J. T. M., SiC/Ti6Al4V functionally graded materials produced by laser melt injection”, Acta Materialia, Vol. 50, p. 2035–2051, 2002.
Pereira, R. F. da C., Oliveira, E. S. D. de, Lima, M. A. G. de A., and Urtiga Filho, S. L., Evaluation of the Multi-Structural Potential of Ni-Co/SiC Nanocomposite Coatings Electrodeposited in API 5L X80 Steel, Materials Research, Vol. 24, No. 2, Article e20200362, 2021.
Qin, L., Xu, J., Lian, J., and Jian, Q., A novel electrodeposited nanostructure Ni coating with grain size gradient distribution, Surface and Coatings Technology, Vol. 203, p. 142–147, 2008.
Vereschaka, A., Tabakov, V., Grigoriev, S., Sitnikov, N., Oganyan, G., Andreev, N., et al., Investigation of wear dynamics for cutting tools with multilayer composite nanostructured coatings in turning constructional steel, Wear, Vol. 420–421, p. 17–37, 2019.
Wang, H., Yao, S., and Matsumura, S., Electrochemical preparation and characterization of Ni-SiC gradient deposit, Journal of Materials Processing Technology, Vol. 145, p. 299–302, 2004.
Wang, Y., Zhou, X., Liang, Z., and Jin, H., Characterization of ultrasonic-assisted electrochemical deposition of Ni-Co-ZrO2 coatings, Coatings, Vol. 8, No. 6, Article 211, 2018.
Zimmerman, A. F., Palumbo, G., Aust, K. T, and Erb, U., Mechanical properties of nickel silicon carbide nanocomposites, Materials Science and Engineering A, Vol. 328, p. 137–146, 2002.

  • Receive Date 11 July 2025
  • Revise Date 17 August 2025
  • Accept Date 25 August 2025