Document Type : Research Paper

Authors

1 Ph.D. Candidate, Department of Petroleum Engineering, Shahid Bahonar University of Kerman, Kerman, Iran

2 Assistant Professor, Department of Petroleum Engineering, Shahid Bahonar University of Kerman, Kerman,Iran.

3 Associate Professor, Department of Mechanical Engineering , Shahid Bahonar University of Kerman, Kerman, Iran

4 Assistant Professor, Department of Petroleum Engineering, Shahid Bahonar University of Kerman, Kerman, Iran

Abstract

Although experimental studies confirmed the effectiveness of nanoparticles in enhanced oil recovery applications, no comprehensive investigation has been carried out to reveal the effect of different subsurface factors on this improvement. Proper application of nanoparticles mainly depends on their ability to travel long distances within a reservoir without agglomeration, retention, and blocking the pore throats. This study strengthens our understanding of the effect of the main subsurface factors on the nanofluid-assisted enhanced oil recovery. To this end, a transport approach utilizing the kinetic Langmuir model is developed and validated using experimental data. After that, the effects of reservoir rock type and its properties (clay content and grain size), the salinity of injected fluid, and the reservoir temperature on the transport and retention of nanoparticles in porous media concerning enhanced oil recovery methods are investigated. Since the concentration of nanoparticles in the injected fluid and on the rock surface (as deposited) control the mobility and wettability alteration, the effect of subsurface factors and salinity of injected fluid on this deposition is also analyzed. The results showed that the rock type and its properties significantly affect the transport and retention of nanoparticles in porous media. Brine salinity also has the most significant impact on the amount of nanoparticles deposited on the rock surface. The surface covered by nanoparticles increased from 10% to 82% after changing salinity from 3 wt % NaCl to the API brine. 

Highlights

  • Transport and retention of nanoparticles determine the performance of EOR processes;
  • The effect of the main subsurface factors on the nanofluid-assisted EOR is examined;
  • The effect of the salinity of the injected fluid on the amount of nanoparticles deposition on rock surface is studied;
  • The degree of wettability alteration is related to the concentration of nanoparticles on the rock surface.

Keywords

Main Subjects

Abdelfatah, E., Kang, K., Pournik, M., Shiau, B. J. B., and Harwell, J., Mechanistic Study of Nanoparticles Deposition and Release in Porous Media: Journal of Petroleum Science and Engineering, Vol. 157, p. 816–832, 2017a.
Abdelfatah, E., Pournik, M., Shiau, B. J. B., and Harwell, J., Mathematical Modeling and Simulation of Nanoparticles Transport in Heterogeneous Porous Media: Journal of Natural Gas Science and Engineering, Vol. 40, p. 1–16, 2017b.
Agista, M. N., A Literature Review and Transport Modelling of Nanoparticles for Enhanced Oil Recovery: University of Stavanger, Norway, 2017.
Ali, J. A., Kolo, K., Manshad, A. K., and Mohammadi, A. H., Recent Advances in Application of Nanotechnology in Chemical Enhanced Oil Recovery: Effects of Nanoparticles on Wettability Alteration, Interfacial Tension Reduction, and Flooding: Egyptian Journal of Petroleum, Vol. 27, No. 4, p. 1371–1383, 2018,
Caldelas, F. M., Experimental Parameter Analysis of Nanoparticle Retention in Porous Media [Ms Thesis: University of Texas at Austin, Austin, Texas, 2010.
Cushen, M., Kerry, J., Morris, M., Cruz-Romero, M., and Cummins, E., Nanotechnologies in The Food Industry–recent Developments, Risks, and Regulation: Trends in Food Science & Technology, Vol. 24, No. 1, p. 30–46, 2012.
Denney, D., Reservoir-Engineering Analysis of Microbial Enhanced Oil Recovery: Journal of Petroleum Technology, Vol. 53, No. 01, p. 57–58, 2001.
El-Amin, M., Salama, A., and Sun, S., A Generalized Power-law Scaling Law for A Two-phase Imbibition in A Porous Medium: Journal of Petroleum Science and Engineering, Vol. 111, p. 159–169, 2013.
El-Amin, M., Salama, A., and Sun, S., Numerical and Dimensional Analysis of Nanoparticles Transport With Two-phase Flow in Porous Media: Journal of Petroleum Science and Engineering, Vol. 128, p. 53–64, 2015.
El-Diasty, A. I., the Potential of Nanoparticles to Improve Oil Recovery in Bahariya Formation, Egypt: An Experimental Study, In Proceedings SPE Asia Pacific Enhanced Oil Recovery Conference 2015, Society of Petroleum Engineers, 2015.
Fang, J., Shan, X.-Q., Wen, B., and Huang, R.-X., Mobility of TX100 Suspended Multiwalled Carbon Nanotubes (MWCNTS) and the Facilitated Transport of Phenanthrene in Real Soil Columns: Geoderma, Vol. 207, p. 1–7, 2013.
Giraldo, J., Benjumea, P., Lopera, S., Cortés, F. B., and Ruiz, M. A., Wettability Alteration of Sandstone Cores by Alumina-based Nanofluids: Energy & Fuels, Vol. 27, No. 7, p. 3659–3665, 2013.
Haroun, M. R., Alhassan, S., Ansari, A. A., Al Kindy, N. A. M., Abou Sayed, N., Abdul Kareem, B. A., and Sarma, H. K., Smart Nano-EOR Process for Abu Dhabi Carbonate Reservoirs, In Proceedings Abu Dhabi International Petroleum Conference and Exhibition2012, Society of Petroleum Engineers, 2012.
Hendraningrat, L., Unlocking the Potential of Hydrophilic Nanoparticles as Novel Enhanced Oil Recovery Method: an Experimental Investigation, 2015.
Hendraningrat, L., Li, S., and Torsæter, O., A Coreflood Investigation of Nanofluid Enhanced Oil Recovery: Journal of Petroleum Science and Engineering, Vol. 111, p. 128–138, 2013a.
Hendraningrat, L., Li, S., and Torsater, O., Effect of Some Parameters Influencing Enhanced Oil Recovery Process Using Silica Nanoparticles: An Experimental Investigation, in Proceedings SPE Reservoir Characterization and Simulation Conference and Exhibition2013b, Society of Petroleum Engineers, 2013.
Hendraningrat, L., and Torsæter, O., Metal Oxide-based Nanoparticles: Revealing Their Potential to Enhance Oil Recovery in Different Wettability Systems: Applied Nanoscience, Vol. 5, No. 2, p. 181–199, 2015.
Hendraningrat, L., and Torsæter, O., Understanding Fluid-fluid and Fluid-rock Interactions in The Presence of Hydrophilic Nanoparticles at Various Conditions, in Proceedings SPE Asia Pacific Oil & Gas Conference and Exhibition2014, Society of Petroleum Engineers, 2014.
Irfan, S. A., Shafie, A., Yahya, N., and Zainuddin, N., Mathematical Modeling and Simulation of Nanoparticle-Assisted Enhanced Oil Recovery—a Review: Energies, Vol. 12, No. 8, p. 1575, 2019.
Karimi, A., Fakhroueian, Z., Bahramian, A., Pour Khiabani, N., Darabad, J. B., Azin, R., and Arya, S., Wettability Alteration In Carbonates Using Zirconium Oxide Nanofluids: EOR Implications: Energy & Fuels, Vol. 26, No. 2, p. 1028–1036, 2012.
Khalil, M., Jan, B. M., Tong, C. W., and Berawi, M. A., Advanced Nanomaterials in Oil and Gas Industry: Design, Application, and Challenges: Applied Energy, Vol. 191, p. 287–310, 2017.
Li, S., Genys, M., Wang, K., and Torsæter, O., Experimental Study of Wettability Alteration During Nanofluid Enhanced Oil Recovery Process and Its Effect On Oil Recovery, in Proceedings SPE Reservoir Characterization and Simulation Conference and Exhibition2015, Society of Petroleum Engineers, 2015.
Li, S., Torsaeter, O., Lau, H. C., Hadia, N. J., and Stubbs, L. P., The Impact of Nanoparticle Adsorption On Transport and Wettability Alteration in Water-wet Berea Sandstone: An Experimental Study: Frontiers in Physics, Vol. 7, p. 74, 2019.
Maghzi, A., Mohebbi, A., Kharrat, R., and Ghazanfari, M., an Experimental Investigation of Silica Nanoparticles Effect on The Rheological Behavior of Polyacrylamide Solution To Enhance Heavy Oil Recovery: Petroleum Science and Technology, Vol. 31, No. 5, p. 500–508, 2013.
Mcelfresh, P. M., Holcomb, D. L., and Ector, D., Application of Nanofluid Technology to Improve Recovery in Oil and Gas Wells, in Proceedings SPE International Oilfield Nanotechnology Conference and Exhibition2012, Society of Petroleum Engineers, 2012.
Metin, C., Bonnecaze, R., and Nguyen, Q., The Viscosity of Silica Nanoparticle Dispersions in Permeable Media: SPE Reservoir Evaluation & Engineering, Vol. 16, No. 03, p. 327–332, 2013.
Murphy, M. J., Experimental Analysis of Electrostatic and Hydrodynamic Forces Affecting Nanoparticle Retention in Porous Media, 2012.
Paosangthong, W., Torah, R., and Beeby, S., Recent Progress on Textile-based Triboelectric Nanogenerators: Nano Energy, Vol. 55, p. 401–423, 2019,
Parvazdavani, M., Masihi, M., and Ghazanfari, M. H., Monitoring the Influence of Dispersed Nanoparticles on Oil–water Relative Permeability Hysteresis: Journal of Petroleum Science and Engineering, Vol. 124, p. 222–231, 2014.
Pu, Y., Leng, J., Wang, D., Wang, J., Foster, N. R., and Chen, J., Recent Progress in The Green Synthesis Of Rare-earth Doped Upconversion Nanophosphors for Optical Bioimaging from Cells To Animals: Chinese Journal Of Chemical Engineering, Vol. 26, No. 10, p. 2206–2218, 2018.
Ragab, A. M. S., and Hannora, A. E., An Experimental Investigation of Silica Nanoparticles for Enhanced Oil Recovery Applications, in Proceedings SPE North Africa Technical Conference and Exhibition2015, Society of Petroleum Engineers,2015.
Rashidi, A., Solaimany Nazar, A., and Radnia, H., Application of Nanoparticles for Chemical Enhanced Oil Recovery: Iranian Journal of Oil & Gas Science and Technology, Vol. 7, No. 1, p. 1–19, 2018.
Roustaei, A., and Bagherzadeh, H., Experimental Investigation of Sio2 Nanoparticles on Enhanced Oil Recovery of Carbonate Reservoirs: Journal of Petroleum Exploration and Production Technology, V. 5, No. 1, p. 27–33, 2015.
Saleh, N., Kim, H.-J., Phenrat, T., Matyjaszewski, K., Tilton, R. D., And Lowry, G. V., Ionic Strength, and Composition Affect The Mobility of Surface-modified Fe0 Nanoparticles in Water-saturated Sand Columns: Environmental Science & Technology, Vol. 42, No. 9, p. 3349–3355,2008.
Salejova, G., Grof, Z., Solcova, O., Schneider, P., and Kosek, J., Strategy for Predicting Effective Transport Properties of Complex Porous Structures: Computers & Chemical Engineering, Vol. 35, No. 2, p. 200–211,2011.
Salem Ragab, A. M., and Hannora, A. E., A Comparative Investigation of Nanoparticle Effects for Improved Oil Recovery–experimental Work, in Proceedings SPE Kuwait Oil and Gas Show and Conference2015, Society of Petroleum Engineers,2015.
Song, S., Peng, C., Gonzalez-Olivares, M., Lopez-Valdivieso, A., and Fort, T., Study on Hydration Layers Near Nanoscale Silica Dispersed in Aqueous Solutions Through Viscosity Measurement: Journal Of Colloid and Interface Science, Vol. 287, No. 1, p. 114–120, 2005.
Tajmiri, M., Mousavi, S. M., Ehsani, M. R., Roayaei, E., And Emadi, A., Wettability Alteration of Sandstone and Carbonate Rocks by Using ZnO Nanoparticles in Heavy Oil Reservoirs: Iranian Journal of Oil & Gas Science and Technology, Vol. 4, No. 4, p. 50–66, 2015,
Tarek, M., And El-Banbi, A. H., Comprehensive Investigation of Effects of Nanofluid Mixtures to Enhance Oil Recovery, in Proceedings SPE North Africa Technical Conference and Exhibition2015, Society of Petroleum Engineers,2015.
Wang, Y., Li, Y., Fortner, J. D., Hughes, J. B., Abriola, L. M., and Pennell, K. D., Transport and Retention of Nanoscale C60 p Aggregates in Water-saturated Porous Media: Environmental Science & Technology, Vol. 42, No. 10, 3588–3594, 2008.
Yu, J., An, C., Mo, D., Liu, N., and Lee, R. L., Study of Adsorption and Transportation Behavior of Nanoparticles in Three Different Porous Media, in Proceedings SPE Improved Oil Recovery Symposium2012, Society of Petroleum Engineers,2012.
Zargartalebi, M., Barati, N., and Kharrat, R., Influences of Hydrophilic and Hydrophobic Silica Nanoparticles on Anionic Surfactant Properties: Interfacial and Adsorption Behaviors: Journal of Petroleum Science and Engineering, Vol. 119, p. 36–43, 2014.
Zhang, T., Modeling of Nanoparticle Transport in Porous Media [Ph.D. Thesis: University of Texas at Austin, 2012.