Research Paper
Chemical Engineering
Hossein Hejazi; Behrouz Bayati; Mohsen Mansouri
Abstract
This study investigated the effect of ethylene-vinyl acetate (EVA) as an inhibitor on wax appearance temperature (WAT) of crude oil in the Iranian oil field using the differential scanning calorimetry (DSC) method. The effect of EVA on the morphology of crude oil wax crystals was examined by a system ...
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This study investigated the effect of ethylene-vinyl acetate (EVA) as an inhibitor on wax appearance temperature (WAT) of crude oil in the Iranian oil field using the differential scanning calorimetry (DSC) method. The effect of EVA on the morphology of crude oil wax crystals was examined by a system equipped with an ocular microscope. The EVA inhibitor has an outstanding performance in reducing the wax appearance temperature of crude oil and prevents the crystallization process and the connection of the growing wax crystals to form a network structure by adsorbing on them. Adding 800 ppm of the EVA inhibitor caused the most significant decrease in the WAT of crude oil at a rate of 26.13 °C and formed smaller crystals and weaker structures at this concentration. Therefore, 800 ppm of the EVA inhibitor was selected as the optimal value.
Research Paper
Petroleum Engineering
Siavash Ashoori; Ehsan Safavi; Jamshid Moghaddasi; Parvin Kolahkaj
Abstract
Formation damage is reported during the secondary and tertiary stages of reservoir lifespan. One of the unpleasant sequences of formation damage caused by fine particles is permeability reduction due to pore plugging and bridging. The fine particles might exist initially in a porous medium or be introduced ...
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Formation damage is reported during the secondary and tertiary stages of reservoir lifespan. One of the unpleasant sequences of formation damage caused by fine particles is permeability reduction due to pore plugging and bridging. The fine particles might exist initially in a porous medium or be introduced by external sources. In addition, there is a variety of particle types and sizes. The current research focuses on the effects of non-swelling clay minerals motions, such as the laminar ones found in Iranian sandstone reservoirs, on permeability. For this purpose, sand packs in various glass bead sizes and containing aluminum oxide as fine particles were designed to scrutinize the motion of fine particles under various pressure differences, flow rates, and concentrations. It was concluded that for each of the three sand packs regarded as the porous media in this study and composed of fine glass beads with different sizes, there is a critical flow rate as a function of glass bead size. For the flow rates lower than the critical flow rate, bridges form stably and lead to the most severe formation damage. After reaching the critical flow rate, the bridges weaken and break, and relative permeability will be independent of the flow rate. It was deduced that permeability reduction and formation damage are directly proportional to particle concentration and inversely proportional to glass bead size.
Research Paper
Petroleum Engineering – Reservoir
Temple N Chikwe; Mudiaga Onojake
Abstract
The geochemical investigation of trace metals in crude oils from some producing oil fields in the Niger Delta, Nigeria, was carried out to ascertain the petroleum source rocks and organic matter deposits. The concentrations of trace metals in crude oil samples obtained from eight producing fields from ...
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The geochemical investigation of trace metals in crude oils from some producing oil fields in the Niger Delta, Nigeria, was carried out to ascertain the petroleum source rocks and organic matter deposits. The concentrations of trace metals in crude oil samples obtained from eight producing fields from Niger Delta, Nigeria, were analyzed using a 700 model Perkin Elmer atomic absorption spectrophotometer. The results showed the following ranges for the trace metals: Cu (0.01–0.04 mg/kg), Fe (0.05–5.90 mg/kg), Ni (0.09–0.72 mg/kg); and V (0.008–1.05 mg/kg). Pb and Zn were lower than 0.01 mg/kg. Trace metal ratios such as V/Ni, V/Fe, and (V/V + Ni) were used to unravel the genetic correlation among the oils. All the crude samples except the sample from Nembe South-2 have a V/N ratio lower than 1.0, indicating that the organic materials produced the petroleum source rock. A cross plot of V/Ni revealed two genetic families for the crude oils, derived from a terrestrial and marine origin, which was confirmed by the ternary plot of V, Ni, and Fe, discriminating the crude oils from the producing fields into two distinct groups. The V/(Ni + V) of smaller than 0.5 showed that most crude oils were deposited in an oxic environment. A cross-plot of V/(Ni + V) and V/Fe showed a weak correlation, suggesting that it could not substitute for the V/Ni ratio in determining the origin and depositional environment of crude oil samples. Therefore, an in-depth knowledge of the concentration of trace metals, especially vanadium and nickel, within an environment during oil exploration is essential in developing new oil locations.
Research Paper
Petroleum Engineering
Nima Hamidian Shoormasti; Seyyedalireza Tabatabaei-Nezhad
Abstract
Shale formations are essential for different disciplines, including wellbore stability studies in petroleum engineering. In shale stability studies, the prediction of transport parameters of water and ions is a significant issue (Farrokhrouz and Asef, 2013). A unique and novel method to address this ...
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Shale formations are essential for different disciplines, including wellbore stability studies in petroleum engineering. In shale stability studies, the prediction of transport parameters of water and ions is a significant issue (Farrokhrouz and Asef, 2013). A unique and novel method to address this subject is the Revil model (Revil et al., 2011), which, unlike previous models, considers physiochemical mechanisms in the pore space and needs a few easily measurable shale properties (Revil et al., 2004). In this paper, for the first time to our knowledge, the Revil model has been extended for salts of multivalent ions. The extended model for water and ion transport through shale has been evaluated against a range of experimental data sets in the literature. The extended Revil model only needs a few shale properties such as cation exchange capacity (CEC), porosity, and grain density, which can be readily measured in the laboratory. Further, in the present work, three parameters ( ) have been considered calibration parameters. In addition to extending the Revil model for multivalent salts, we derived a simplified equation to estimate ion selectivity (IS) and a proof for the conjecture that IS correlates with membrane efficiency (ME). Focusing on the data set of Albazali (2005), a complete matching could be obtained by adjusting calibration parameters for each test data. In the case of adjusting all experiments with only three standard calibration parameters, the prediction was not satisfactory. However, the “intact-anion method” results were more accurate than the “Donnan method”. When multiple sets of ME data in a broader concentration range, including low concentrations, were plotted along with high-concentration data, correlativity was significant (R2 > 0.9). Further, a sensitivity analysis of the model parameters was performed. Our findings pave the way for the appropriate mechanistic approach to investigating and handling practical engineering challenges associated with shale.
Research Paper
Petroleum Engineering
Yaser Ahmadi
Abstract
Using nanoparticles for adsorbing asphaltene is an efficient method for upgrading actual oil samples compared to other expensive mechanical treatments or even solvents, such as n-pentane and n-heptane, and surfactants. This study uses nickel–zeolite oxide nanoparticles for asphaltene adsorption ...
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Using nanoparticles for adsorbing asphaltene is an efficient method for upgrading actual oil samples compared to other expensive mechanical treatments or even solvents, such as n-pentane and n-heptane, and surfactants. This study uses nickel–zeolite oxide nanoparticles for asphaltene adsorption and solving asphaltene precipitation problems. Although nickel–zeolite oxide nanoparticles have been used in previous studies as an asphaltene adsorbent, observing the relationship between asphaltene adsorption on their surface and asphaltene precipitation in the presence of nanoparticles during the actual process is not covered. For addressing this relation, we performed a series of experiments included Fourier-transform infrared spectroscopy (FTIR), CO2–oil interfacial tension tests, Langmuir and Freundlich isotherm models, and natural depletion tests in the presence of nickel–zeolite oxide nanoparticles. The Langmuir model better fitted the adsorption data than the Freundlich model, which shows that the adsorption occurs on a homogeneous surface with monolayer coverage. Based on the CO2–oil interfacial tension results, there are two different slope forms in interfacial tension readings as pressure increases from 150 to 1650 psi. Due to asphaltene aggregation, the second slope (900–1650 psi) is slower than the first one (150–900 psi). Three pressures of 1350, 1500, and 1650 psi and nickel–zeolite oxide nanoparticles at a concentration of 30 ppm were selected for the natural depletion tests, and the basis of selection was high-efficiency adsorption at these points. As pressure decreased from 1650 to 1350 psi, asphaltene precipitation changed from 8.25 to 10.52 wt % in the base case, and it varied from 5.17 to 7.54 wt % in the presence of nickel–zeolite oxide at a concentration of 30 ppm. Accordingly, nickel–zeolite oxide nanoparticles adsorbed asphaltene on their surface correctly, and the amount of asphaltene precipitation decreased in the presence of nickel–zeolite oxide nanoparticles.
Research Paper
Petroleum Engineering – Drilling
Aref Khazaei; Reza Radfar; Abbas Toloie Eshlaghy
Abstract
Iran is one of the largest oil and gas producers in the world. Intelligent manufacturing approaches can lead to better performance and lower costs of the well drilling process. One of the most critical issues during the drilling operation is the wellbore stability. Instability of wellbore can occur at ...
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Iran is one of the largest oil and gas producers in the world. Intelligent manufacturing approaches can lead to better performance and lower costs of the well drilling process. One of the most critical issues during the drilling operation is the wellbore stability. Instability of wellbore can occur at different stages of a well life and inflict heavy financial and time damage on companies. A controllable factor can prevent these damages by selecting a proper drilling mud weight. This research presents a drilling mud weight estimator for Iranian wells using deep-learning techniques. Our Iranian data set only contains 900 samples, but efficient deep-learning models usually need large amounts of data to obtain acceptable performance. Therefore, the samples of two data sets related to the United Kingdom and Norway fields are also used to extend our data set. Our final data set has contained more than half-million samples that have been compiled from 132 wells of three fields. Our presented mud weight estimator is an artificial neural network with 5 hidden layers and 256 nodes in each layer that can estimate the mud weight for new wells and depths with the mean absolute error (MAE) of smaller than ±0.039 pound per gallon (ppg). In this research, the presented model is challenged in real-world conditions, and the results show that our model can be reliable and efficient in the real world.
Research Paper
Electrical Engineering – Control
Karim Salahshoor; Seyed morteza Hoseini
Abstract
The model-based optimization of the waterflooding process has found significant scope for improving the economic life-cycle performance of oil fields due to geological and economic uncertainties compared to conventional reactive strategies. This paper proposes a new frequency-based system identification ...
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The model-based optimization of the waterflooding process has found significant scope for improving the economic life-cycle performance of oil fields due to geological and economic uncertainties compared to conventional reactive strategies. This paper proposes a new frequency-based system identification method to identify a robust multi-input, multi-output (MIMO) surrogate model for an oil reservoir under waterflooding process so as to describe all the injector-producer relationships. In contrast to the conventional modeling methods, the proposed data-driven modeling approach uses the available injection and production rates as the reservoir input–output data. Meanwhile, it includes a structured-bounded uncertainty model in the form of norm-bounded state-space function blocks to account for uncertainties, facilitating the identified model employed in robust control methodology using linear matrix inequality (LMI) problem formulation so as to eliminate the effect of model uncertainty. The identified MIMO surrogate model is integrated with a desired nonlinear net present value (NPV) objective function in a multi-input, single-output (MISO) system configuration to synthesize a model-based optimization prediction for economical operation and production of oil from oil reservoirs under both geological and economic uncertainties. The introduced approach is implemented on the “EGG model” as a well-recognized three-dimensional synthetic oil reservoir with eight water injection wells and four oil production wells. The results demonstrate that economic performance prediction of the oil reservoir, having an uncertain permeability field, lies in the evaluated bound of the uncertainty model. Waterflooding is a well-known method for increasing oil production. A significant amount of time and effort is required even for high-performance processors to numerically simulate a reservoir with thousands of grid blocks. On the other hand, there is a high uncertainty level in oil reservoir model-based economic optimization due to limited information about geological model parameters. Employing robust control methods can provide robustness for the performance and stability of the control system against model norm-bounded uncertainty. However, in all standard identification methods, it is assumed that the uncertainties in the model can be accommodated in the form of noise. Therefore, the challenge of using the models estimated from the standard identification approach in robust control methods can mainly be considered an essential subject. This paper presents a new frequency-based modeling approach to identify a surrogate model and uncertainty modeling for the waterflooding process with the ease of being employed in robust control methods. A desirable relationship is obtained between the injection rate and the economic production function to model the dynamics of the reservoir using the identification of the surrogate model. Then, the concept of structure bounded uncertainty modeling is presented to describe the model geological uncertainty.