Mohammadreza Shishesaz; Davood Jafari; davood zaarei; Iman Danaee
Abstract
Different amounts of nanoclay were incorporated into the acrylic resin matrix at 0, 1, 3, and 5 wt.% loadings. The coatings were applied on low carbon steel plates. Optical microscopy, sedimentation test, transmission electron microscopy, and X-ray diffraction were employed to investigate the dispersion ...
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Different amounts of nanoclay were incorporated into the acrylic resin matrix at 0, 1, 3, and 5 wt.% loadings. The coatings were applied on low carbon steel plates. Optical microscopy, sedimentation test, transmission electron microscopy, and X-ray diffraction were employed to investigate the dispersion of nanoclay in matrix. The corrosion resistance of coatings was evaluated by electrochemical impedance spectroscopy, polarization measurement, and salt spray test. In addition, pull-off and cross-cut tests were used for the assessment of coating adhesion to the substrate. The results indicated that the anti-corrosive properties of the acrylic resin were obviously increased by the addition of nanoclay. The nanocomposite coatings containing 3 wt.% clay showed the best corrosion resistance. Finally, the nanocomposites containing 1 and 3 wt.% showed the highest adhesion to the substrate.
Iman Moghri; Mansoor Farzam; Mohammadreza Shishesaz; Davood Zaarei
Abstract
In this study, nanocomposite coatings based on polyurethane cerium nitrate montmorillonite (MMT) were prepared, applied on carbon steel substrates, and investigated. The nanocomposite coatings were successfully prepared by the effective dispersing of nanoparticles in polyurethane resin by mechanical ...
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In this study, nanocomposite coatings based on polyurethane cerium nitrate montmorillonite (MMT) were prepared, applied on carbon steel substrates, and investigated. The nanocomposite coatings were successfully prepared by the effective dispersing of nanoparticles in polyurethane resin by mechanical and sonication processes. The state of dispersion, dissolution, and incorporation were characterized by optical microscopy, sedimentation tests, and transmission electron microscopy. The structure and properties of the nanocomposite coatings were investigated by X-ray diffraction and anticorrosive properties of the nanocomposites were studied by Tafel polarization measurements. The experimental results showed that the PU/MMT/Cerium nitrate nanocomposite coatings were superior to the neat PU in corrosion protection. In addition, it was observed that the corrosion protection of the nanocomposite coatings was improved as the clay and cerium nitrate loadings were increased to 4 wt.% to 2 wt.% respectively.
Hamid Reza Zamanizadeh; Mohammad Reza Shishesaz; Iman Danaee; Davood Zaarei
Abstract
In this study, the corrosion resistance of a bituminous coating reinforced with different ratios of nanoclay pigment was studied. To make nanocomposite coatings, 2, 3, and 4 wt.% of clay (Cloisite Na+) were incorporated into water emulsified bitumen. The coatings were applied to steel 37. Optical microscopy ...
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In this study, the corrosion resistance of a bituminous coating reinforced with different ratios of nanoclay pigment was studied. To make nanocomposite coatings, 2, 3, and 4 wt.% of clay (Cloisite Na+) were incorporated into water emulsified bitumen. The coatings were applied to steel 37. Optical microscopy and X-ray diffraction (XRD) were used to characterize the nanocomposite structure. In order to investigate the anticorrosion behavior of the coatings, electrochemical impedance spectroscopy (EIS) and direct current polarization techniques were used. The results show that the coatings containing nanoclay have better performance compared to the neat bitumen. Moreover, it was revealed that the corrosion resistance of the nanocomposite increased as the clay loading increased up to 4 wt.%.
