Masoumeh Tajmiri; Seyed Mousa Mousavi; Mohammad Reza Ehsani; Emad Roayaei; Ali Emadi
Abstract
Efforts to enhance oil recovery through wettability alteration by nanoparticles have been attracted in recent years. However, many basic questions have been ambiguous up until now. Nanoparticles penetrate into pore volume of porous media, stick on the core surface, and by creating homogeneous water-wet ...
Read More
Efforts to enhance oil recovery through wettability alteration by nanoparticles have been attracted in recent years. However, many basic questions have been ambiguous up until now. Nanoparticles penetrate into pore volume of porous media, stick on the core surface, and by creating homogeneous water-wet area, cause to alter wettability. This work introduces the new concept of adding ZnO nanoparticles by an experimental work on wettability alteration and oil recovery through spontaneous imbibition mechanism. Laboratory tests were conducted in two experimental steps on four cylindrical core samples (three sandstones and one carbonate) taken from a real Iranian heavy oil reservoir in Amott cell. In the first step, the core samples were saturated by crude oil. Next, the core samples were flooded with nanoparticles and saturated by crude oil for about two weeks. Then, the core samples were immersed in distilled water and the amount of recovery was monitored during 30 days for both steps. The experimental results showed that oil recovery for three sandstone cores changed from 20.74, 4.3, and 3.5% of original oil in place (OOIP) in the absence of nanoparticles to 36.2, 17.57, and 20.68% of OOIP when nanoparticles were added respectively. Moreover, for the carbonate core, the recovery changed from zero to 8.89% of OOIP by adding nanoparticles. By the investigation of relative permeability curves, it was found that by adding ZnO nanoparticles, the crossover-point of curves shifted to the right for both sandstone and carbonate cores, which meant wettability was altered to water- wet. This study, for the first time, illustrated the remarkable role of ZnO nanoparticles in wettability alteration toward more water-wet for both sandstone and carbonate cores and enhancing oil recovery.
Javad Esmaili; Mohammad Reza Ehsani
Abstract
In this paper, the development of a new potassium carbonateon alumina support sorbent prepared by impregnating K2CO3 with an industrial grade of Al2O3 support was investigated. The CO2 capture capacity was measured using real flue gas with 8% CO2 and 12% H2O in a fixed-bed reactor at a temperature of ...
Read More
In this paper, the development of a new potassium carbonateon alumina support sorbent prepared by impregnating K2CO3 with an industrial grade of Al2O3 support was investigated. The CO2 capture capacity was measured using real flue gas with 8% CO2 and 12% H2O in a fixed-bed reactor at a temperature of 65 °C using breakthrough curves. The developed sorbent showed an adsorption capacity of 66.2 mgCO2/(gr sorbent). The stability of sorbent capture capacity was higher than the reference sorbent. The SO2 impurity decreased sorbent capacity about 10%. The free carbon had a small effect on sorbent capacity after 5 cycles. After 5 cycles of adsorption and regeneration, the changes in the pore volume and surface area were 0.020 cm3/gr and 5.5 m2/gr respectively. Small changes occurred in the pore size distribution and surface area of sorbent after 5 cycles.
Sahar Afzal; Mohammad Nikookar; Mohammad Reza Ehsani; Emad Roayaei
Abstract
Nanotechnology has the potential to introduce revolutionary changes to several areas of oil and gas industry such as exploration, production, enhanced oil recovery, and refining. In this paper, the effect of different concentrations of Fe2O3 nanoparticles as a catalyst on the heavy oil viscosity at various ...
Read More
Nanotechnology has the potential to introduce revolutionary changes to several areas of oil and gas industry such as exploration, production, enhanced oil recovery, and refining. In this paper, the effect of different concentrations of Fe2O3 nanoparticles as a catalyst on the heavy oil viscosity at various temperatures is studied. Furthermore, the effect of a mixture of Fe2O3 nanoparticles and steam injection on heavy oil recovery is studied in laboratory. The experimental tests show that some of these nanoparticles decrease the heavy oil viscosity less than 50% at certain concentrations at different temperatures. The reason for this viscosity reduction is that, similar to a catalyst, these nanoparticles activate some reactions. Our results of steam injection tests show that the injection of a Fe2O3 nanoparticle mixture increases heavy oil recovery because of cracking reactions which crack the C-S, C=C, and C≡C bonds of the heavy components of heavy oil and change them to light components.
