Chemical Engineering – Gas Processing and Transmission
Mahnaz Pourkhalil
Abstract
A series of copper oxide (CuOx) catalysts supported by oxidized multi-walled carbon nanotubes (OMWNT’s) were prepared by the wet impregnation method for the low temperature (200 °C) selective catalytic reduction of nitrogen oxides (NOx) using NH3 as a reductant agent in the presence of excess ...
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A series of copper oxide (CuOx) catalysts supported by oxidized multi-walled carbon nanotubes (OMWNT’s) were prepared by the wet impregnation method for the low temperature (200 °C) selective catalytic reduction of nitrogen oxides (NOx) using NH3 as a reductant agent in the presence of excess oxygen. These catalysts were characterized by FTIR, XRD, SEM-EDS, and H2-TPR methods. The response surface methodology was employed to model and optimize the effective parameters in the preparation of CuOx/OMWNT’s catalysts in NOx removal by NH3-SCR process. Three experimental parameters, including calcination temperature, calcination time, and CuOx loading were chosen as the independent variables. The central composite design was utilized to establish a quadratic model as a functional relationship between the conversion of NOx as a response factor and independent variables. The ANOVA results showed that the NOx conversion is significantly affected by calcination temperature and CuOx loading. At the optimal values of the studied parameters, the maximum conversion of NOx, 86.3 %, was obtained at a calcination temperature of 318 °C, a calcination time of 3.4 hr., and CuOx loading of 16.73 wt.%; the reaction conditions was as follows: T= 200 °C, P= 1 bar, NO = NH3 = 900 ppm, O2 = 5 vol.%, and GHSV = 30,000 hr.−1. The regression analysis with an R2value of 0.9908 revealed a satisfactory correlation between the experimental data and the values predicted for the conversion of NOx. The XRD and H2-TPR results of the best catalyst showed that the formation of CuO as the dominant phase of CuOx is the key factor in low temperature selective catalytic reduction (SCR) process.
Chemical Engineering
Mahnaz Pourkhalil; Saeideh Tasharrofi
Abstract
Cobalt oxide catalysts supported on oxidized multi-walled carbon nanotubes (MWCNT) for the low-temperature catalytic oxidation of carbon monoxide were prepared by an impregnation-ultrasound method. These catalysts were characterized by N2 adsorption/desorption, TEM, XRD, Raman, and H2-TPR methods. The ...
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Cobalt oxide catalysts supported on oxidized multi-walled carbon nanotubes (MWCNT) for the low-temperature catalytic oxidation of carbon monoxide were prepared by an impregnation-ultrasound method. These catalysts were characterized by N2 adsorption/desorption, TEM, XRD, Raman, and H2-TPR methods. The XRD and Raman results indicated that the phase of the synthesized cobalt oxide was in the Co3O4 form. The effects of cobalt oxide loading and reaction temperature were studied on the catalytic oxidation conversion of carbon monoxide. The TEM image of the best catalyst (14 wt.% metal oxide loading) revealed a good dispersion of Co3O4 over the surface of the support with an average particle size of 11-16 nm. Under the reaction conditions of T= 200-250 °C, P=1 bar, CO = 600 ppm, O2 = 5 vol.%, GHSV = 30,000 hr.−1, and Co3O4= 14 wt.%, CO conversion was 91%.
