Chemical Engineering
Ahad Ghaemi; Vahid Hashemzadeh; Shahrokh Shahhosseini
Abstract
In this research, the reactive absorption of carbon dioxide in an aqueous solution of NH3, H2O, and NaOH has experimentally been investigated. The experiments were carried out in an absorption pilot plant in different operational conditions. The composition and temperature of both gas and liquid phases ...
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In this research, the reactive absorption of carbon dioxide in an aqueous solution of NH3, H2O, and NaOH has experimentally been investigated. The experiments were carried out in an absorption pilot plant in different operational conditions. The composition and temperature of both gas and liquid phases were obtained during the column height. The concentration of molecular and ionic species in the liquid phase was calculated using the principles of electrolyte and Pitzer model. In the experiments, the effect of sodium hydroxide concentration on carbon dioxide absorption was considered. The results revealed that the concentrations of ionic and molecular species in the liquid phase drastically influence the absorption rate of carbon dioxide. Also, the results showed that the absorption rate of carbon dioxide was increased by increasing ammonia and sodium hydroxide concentration.
Hadi Zolfaghari; Alireza Zebarjadi; Omid Shahrokhi; Mohammad Hosein Ghazanfari
Abstract
Several studies have shown that oil recovery significantly increased by low salinity water flooding (LSWF) in sandstones. However, mechanism of oil recovery improvement is still controversial. CO2 that develops buffer in presence of water is expected as a deterrent factor in LSWF efficiency based on ...
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Several studies have shown that oil recovery significantly increased by low salinity water flooding (LSWF) in sandstones. However, mechanism of oil recovery improvement is still controversial. CO2 that develops buffer in presence of water is expected as a deterrent factor in LSWF efficiency based on mechanism of IFT reduction due to pH uprising. No bright evidence in literature supports this idea. Here, a set of core floods including a pair of CO2 WAG and a pair of water injection tests are conducted and, the efficiency of LSWF and high salinity water flooding (HSWF) were compared for each pair. HSWF was followed by LSWF in tertiary mode. Results showed that not only CO2 does not deteriorate LSWF recovery efficiency, but also improves recovery. Since CO2-low salinity WAG showed best performance among types by constant pore volume injected. Positive results in both secondary and tertiary modes with Kaolinite free samples used here showed that Kaolinite release is not the critical phenomenon in LSWF brisk performance. Also different pressure behaviour of CO2 WAG processes in comparison with reported behaviour of LSWF proves that LSWF performance may not depend on how pressure changes through flooding.
